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Benzoic Acid
HDPE Drums

Benzoic Acid

ELPROTECTTM – BZA

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Benzoic acid is a versatile aromatic carboxylic acid found naturally in many plants, valued for its antimicrobial, preservative, and pH-adjusting properties, widely utilized in personal care, food,

CAS Number

65-85-0

HS Code

2916.31.10

INCI Name

Benzoic Acid

Molecular Formula

C₇H₆O₂

Home/Products/Benzoic Acid

Benzoic Acid

ELPROTECTTM – BZA

Benzoic acid is a versatile aromatic carboxylic acid found naturally in many plants, valued for its antimicrobial, preservative, and pH-adjusting properties, widely utilized in personal care, food, and pharmaceutical applications due to its broad-spectrum efficacy, stability

CAS Number

65-85-0

INCI Name

Benzoic Acid

HS Code

2916.31.10

Molecular Formula

C₇H₆O₂

Get Pricing for This Product

Need pricing? Request a quote for this product and we'll get back to you shortly.

Speed Up Your Sample Testing Process

We deliver domestic samples within 24 - 48 hours, helping you evaluate products and move to procurement without delays.

Benzoic Acid
HDPE Drums

Product Specification

AppearanceWhite to yellow-beige to orange solid; powder; needles
Molecular Weight (G/Mol)122.12
Density1.08
Refractive Index1.504
Ph3.66(1 mM solution);3.12(10 mM solution);2.6(100 mM solution)

Physical Properties

PropertySpecification
AppearanceWhite to yellow-beige to orange solid; powder; needles
Molecular Weight (G/Mol)122.12
Density1.08
Refractive Index1.504
Ph3.66(1 mM solution);3.12(10 mM solution);2.6(100 mM solution)

Chemical Properties

PropertySpecification
Pka4.19(at 25℃)
Water SolubilitySlightly soluble. 0.34 g/100 mL

Thermal Properties

PropertySpecification
Boiling Point249 °C(lit.)
Melting Point121-125 °C(lit.)
Flash Point250 °F

Processing Methods & Reference Formulations

A. Hair Anti-Dandruff Shampoo

Add benzoic acid during the cooling phase to avoid degradation and maintain stability.

Key IngredientsIndicative Dosage (% w/w)
Sulphur0.75%
Salicylic acid0.5–1.75%
Benzoic acid1.0–2.0 %
Sodium lauryl sulphate20%
Urea0.75%
Citric acid0.5%
Sodium EDTA0.5%
Guar gum1.5%
Tween 800.5%
Distilled water65-75%

B. Cosmetic Ointment

Use benzoic acid in combination with emulsifiers to improve its distribution in semi-solid bases. Always verify the final pH of the ointment to ensure it remains within the effective antimicrobial range.

Key IngredientsIndicative Dosage (% w/w)
10–12%
Salicylic acid0.5%
White vaseline62%
Stearic acid10%
Castor oil4%
Camphor1%
Sodium dodecyl benzene sulfonate0.9%
Ethylparaben0.1%

C. Facial cleansers

Add Benzoic Acid to the water phase of facial cleanser formulations. Dissolve it fully with gentle heating if needed, and pair with other preservatives for broad-spectrum protection.

Key IngredientsIndicative Dosage (% w/w)
65%
3%
Sodium Lauroyl Sarcosinate (30% in water)4.4%
Benzoic Acid0.2%
Disodium EDTA0.1%
PEG-200 Hydrogenated Glyceryl Palmate0.3%
PEG-7 Glyceryl Cocoate0.3%
PEG-752%
Fragrance0.25%
Citric Acid0.8%

D. Moisturizering lotion

Add Benzoic Acid to the water phase of the moisturizer. Dissolve it with gentle heating if necessary, and consider combining it with other preservatives to broaden antimicrobial coverage.

Key IngredientsIndicative Dosage (% w/w)
5%
Stearic Acid3%
Cetyl Alcohol2%
Dimethicone2%
Propylene Glycol3%
Benzoic Acid0.2%
Phenoxyethanol0.5%
Tocopherol (Vitamin E)0.1%
Fragrance0.2%
Citric Acid0.1%
Aqua80-90%

Dosing Guidelines

A. Dosing by Application

ProductsAuthorized dosage %
Ointments/Creams0.5-2.5%
Sunscreen0.2-0.5%
Hair Shampoo0.2-2.5%

About Benzoic Acid

About Benzoic Acid

Regulatory Compliance

RegionMax Allowed LevelNotesCertification Body
China-China Regulation-
Japan-MHLW – Ministry of Health, Labour and Welfare-
New Zealand-States that benzoic acid is safe for use for preservative and non-preservative purposes in cosmetic rinse-off products at a maximum concentration of 2.5 % and in cosmetic oral-care products upto 1.7 %, and in leave-on products up to 0.5 %.-
United States5%The CIR considers the chemical (benzoic acid and its salts) to be safe for use at a maximum allowed concentrations of 5 % (as acid)FDA
European Union-States that benzoic acid is safe for use for preservative and non-preservative purposes in cosmetic rinse-off products at a maximum concentration of 2.5 % and in cosmetic oral-care products upto 1.7 %, and in leave-on products up to 0.5 %.-

FAQs - Benzoic Acid

At what pH is benzoic acid most effective as a preservative?
Benzoic acid exhibits optimal antimicrobial activity below pH 4.5, where a significant portion remains in the undissociated form that can penetrate microbial cell membranes. Its efficacy decreases markedly above pH 5.0.
How does benzoic acid compare to sodium benzoate as a preservative?
Benzoic acid is less water-soluble but more effective at lower pH values. Sodium benzoate, on the other hand, offers better water solubility but requires acidic conditions to convert to the active benzoic acid form.
What concentration of benzoic acid is typically used in personal care products?
Effective concentrations generally range from 0.1–0.5% in rinse-off products and 0.1–0.3% in leave-on formulations, subject to regional regulatory limits.
Can benzoic acid cause skin sensitization?
Benzoic acid has low sensitization potential at typical use levels, though individuals with compromised skin barriers or certain metabolic conditions may experience irritation or sensitivities.
How can benzoic acid be incorporated into complex formulations?
For optimal dispersion, benzoic acid should be dissolved in the heated aqueous phase (above 70°C) or pre-dissolved in alcohols, glycols, or oils before being added to formulations.

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